ASTM E415 Analysis of Carbon and Low-Alloy Steel by Spark Atomic Emission Spectrometry

ASTM E415 Analysis of Carbon and Low-Alloy Steel by Spark Atomic Emission Spectrometry Scope:

The ASTM E415 is a standard test technique for spark atomic emission spectrometry examination of carbon and low-alloy steel. This test method applies to specimens with a diameter large enough to overlap and seal the bore of the spark stand hole. This test technique covers routine control analysis in iron and steelmaking activities as well as material analysis. It is intended for specimens that have been chill-cast, rolled, or forged. 

The spectrometric analysis of metals and alloys in this test method is primarily aimed to ensure that such materials meet compositional standards. All users of this test technique are presumed to be analysts capable of completing conventional laboratory operations skillfully and securely.

The compliance with compositional specifications of coatings is determined by the ASTM E415-21 test method. This helps prevent material failure and leads to better quality production. The condensation tests of coatings help with specification acceptance, quality control, research, and development of coatings and materials. 

Test Procedure:

The ASTM E415 test method proceeds with the production of capacitor discharge between the disk specimen and electrode. The discharge is stopped at a predetermined intensity time integral of a selected iron line, or at a predetermined period, and the analytical lines’ respective radiant energies are recorded. By evacuating the spectrometer or using a vacuum ultraviolet (VUV) transparent gas and flushing the spark chamber with argon, the absorption of the radiation by air in this region is overcome. 

A capacitor discharge is created between the flat, ground surface of the disc specimen and a conically shaped electrode in accordance with the ASTM E415 test protocol. The discharge is stopped at a predetermined intensity time integral of one of the iron lines, or at a predetermined time, and the relative radiant energies of the analytical lines are recorded. The vacuum ultraviolet area contains the most sensitive lines of arsenic, boron, carbon, nitrogen, phosphorus, sulphur, and tin. By vacating the spectrometer and flushing the spark chamber with argon, the absorption of the radiation by air in this location is overcome.

Video 01: Spectrometer testing of low-alloy steel

Specimen Size:

The specimen thickness might vary considerably depending on the design of the spectrometer stand, according to ASTM E415; however, a thickness between 10 mm and 38 mm has been determined to be most practical.

Data:

When reference materials and specimens are of similar metallurgical condition and composition, according to the ASTM E415 test procedure, better results are expected. It is not, however, needed in all cases where this standard is used.

The mass fractions of the elements are determined from the analytical curves and rounding of test results is performed in accordance with the rounding method of practice E29.

Conclusion:

The ASTM E415 test method is specifically important for the quality assurance and durability check of coatings. A detailed analysis is performed and various characteristics are determined.