ASTM D2863 Limiting Oxygen Index (LOI) Testing for Plastics & Textiles

ASTM D2863 is a test method for measurement of the minimum concentration of oxygen, in an oxygen-nitrogen mixture present in a plastic sample, that supports Candle-like Plastic combustion (oxygen index).

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    ASTM D2863 Limiting Oxygen Index (LOI) Testing for Plastics & Textiles

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    • Overview
    • Scope, Applications, and Benefits
    • Test Process
    • Specifications
    • Instrumentation
    • Results and Deliverables

    Overview

    ASTM D2863 defines a standardised method for measuring the minimum concentration of oxygen in an oxygen-nitrogen mixture that will support flaming combustion of a plastic material — a value known as the Limiting Oxygen Index (LOI) or Oxygen Index (OI). Since normal air contains approximately 21% oxygen, materials with an LOI above 21% are considered self-extinguishing in air, while those below 21% will sustain burning.

    The test involves supporting a specimen vertically in a transparent glass chimney, igniting the top of the specimen, and then flowing a controlled mixture of oxygen and nitrogen upward through the chimney. The oxygen concentration is systematically adjusted until the minimum concentration that just supports combustion for a specified duration or burn length is identified. This value directly reflects the inherent flammability behaviour of the material.

    Scope, Applications, and Benefits

    Scope

    ASTM D2863 evaluates:

    • Limiting oxygen index (LOI) of plastic materials
    • Minimum oxygen concentration for sustained combustion
    • Effect of flame retardant additives on LOI
    • Comparative flammability ranking of polymers
    • Influence of specimen orientation on burning behavior
    • Effect of thickness on oxygen index values

    Applications

    • Flame retardant polymer formulation development
    • Electrical and electronic enclosure materials
    • Building and construction plastic components
    • Transportation interior materials (aviation, rail)
    • Wire and cable insulation qualification
    • Textile and fibre flame retardancy evaluation
    • Research and development in fire science

    Benefits

    • Provides a precise numerical flammability index
    • Enables rapid screening of flame retardant effectiveness
    • Supports comparative ranking of polymer flammability
    • Guides flame-retardant additive selection and loading
    • Provides data for fire safety material approvals
    • Applicable to a wide range of polymer types

    Test Process

    Specimen Preparation

    Specimens are cut or molded to the standard geometry and conditioned.

    1

    Gas Flow Setup

    Oxygen and nitrogen flow rates are set to achieve the target oxygen concentration.

    2

    Ignition

    The top surface of the specimen is ignited with the standard igniter.

    3

    Concentration Adjustment

    Oxygen concentration is incrementally adjusted to find the minimum value supporting sustained burning.

    4

    Technical Specifications

    ParameterDetails
    Specimen OrientationVertical
    Applicable MaterialsPlastics, polymer sheets, films, laminated and cellular materials
    Specimen ThicknessUp to 10.5 mm (self-supporting materials)
    Test EnvironmentControlled gas flow and ambient laboratory conditions
    Specimen TypesVertical bars, sheets, films, and flexible specimens

    Instrumentation Used for Testing

    • Oxygen index test column (glass chimney)
    • Precision oxygen and nitrogen gas flow controllers
    • Oxygen analyser / concentration monitor
    • Specimen holder and ignition torch
    • Stopwatch/timer
    • Data recording system

    Results and Deliverables

    • Limiting oxygen index (LOI) value
    • Combustion behavior observations
    • Effect of flame retardant level on LOI (comparative)
    • Specimen burn length and time data
    • Flammability classification report

    Frequently Asked Questions

    It measures the minimum concentration of oxygen required to support continuous burning of a plastic specimen.

    LOI stands for Limiting Oxygen Index, expressed as the percentage of oxygen in an oxygen–nitrogen mixture needed for sustained combustion.

    A higher LOI value means better flame resistance and lower flammability.

    Plastics, films, sheets, foams, laminates, and other polymer-based materials can be tested.

    It is widely used in plastics, aerospace, automotive, cable insulation, electronics, and construction materials industries.

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